Acetaldehyde is a colorless mobile liquid that is flammable and miscible with water. Reacts with mercury and silver oxides to form shocksensitive compounds handling chemicals safely 1980. Safety data sheet creation date 26sep2009 revision date 14feb2020 revision number 3 1. Ac148530000, ac148530250, ac148530500, ac14853, ac148532500 synonyms. Safety data sheet according to 29cfr19101200 and ghs rev. This safety data sheet has been written in conformity with the regulation ue 4532010. Firstaid measures remove victim to fresh air and keep at. Sigmaaldrich offers a number of acetaldehyde products. Person responsible for the safety data sheet with email address. Identification of the substancemixture and of the companyundertaking date issued 05.
Prolonged or repeated skin contact may cause dermatitis. Articles of acetaldehyde ammonia trimer are included as well. Classes of incompatible chemicals should be segregated from each other during storage, according to hazard class. In case of eye contact rinse thoroughly with plenty of water for at least 15 minutes and consult a. Ammonia is incompatible or has potentially hazardous reactions with silver. Acetaldehyde ammonia can affect you when breathed in and by passing through your skin. Fluka 09682 page 1 of 7 sigmaaldrich material safety data sheet version 4. None information in this msds is from available published sources and is believed to be accurate. Please ensure that this msds is received by the appropriate person. Sigmaaldrich 00070 page 3 of 9 if inhaled if breathed in, move person into fresh air. Kinetics of the condensation of acetaldehyde with ammonia. Acetaldehyde ammonia trimer is a reagent used in the synthesis of amines by hydrogenation and as a precursor to the production of ammonia. Ingestion is an unlikely route of exposure for a gas.
Chemical name common name and synonyms cas number % acetaldehyde ammonia trimer, 58052805 trihydrate 100 4. It readily decomposes into acetaldehyde and ammonia when heated, causing the hazards of these substances. The acetaldehydeammonia trimer is a molecule of interest in organic synthesis, since it can be used as a substrate in many reactions involving acetaldehyde or ammonia. Page 1 of 7 propionaldehyde cas no 123386 material safety data sheet sds msds section 1. Material safety data sheet acetaldehyde msds section 1. First aid measures general advice consult a physician. The transport of liquefied ammonia in a tank or bulk container made of quenched and tempered steel is prohibited unless the liquefied ammonia contains not less than 0. Printed in northern ireland kinetics of the condensation of acetaldehyde with ammonia y. Safety data sheet eastmantm acetaldehyde version 2. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Before mixing any chemicals, refer to this partial list, the chemicals msdss or call olsc at 43282 to verify compatibility. Ammonia is capable of reacting with some heavy metal compounds gold, silver, mercury to produce. Ammonia, anhydrous safety data sheet 302 08312017 en english sds ref 302 417 symptomsinjuries after ingestion. Breathing acetaldehyde ammonia can irritate the nose, throat, and lungs causing coughing andor shortness of breath.
The pure material is colourless but samples often appear light yellow or slightly beige due to the degradation by oxidation. Product identifier product name ammonia solution 24,9% chemical name amonium hydroxide synonyms ammonia solution, ammonia water cas no. Eye, nose, and throat irritation occurred in humans exposed to lowtomoderate air levels of acetaldehyde. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. Irrigate the nose and mouth continuously for 15 minutes. Acetaldehyde ammonia trimer 58052805 tcia0201 spectrum. Material safety data sheet acetaldehyde ammonia trimer, 98%. Ab achema safety data sheet ammonia solution azo nox av2. Identification of the substancemixture and of the companyundertaking. Moderate fire and explosion hazard when exposed to heat or flame. Ammonia is capable of reacting with some heavy metal compounds gold, silver, mercury to. Repeated exposure can cause headache, nausea, vomiting, loss of appetite and weight. Anhydrous ammonia has potentially explosive reactions with strong oxidizers.
In limited studies on human volunteers, acetaldehyde is mildly irritating to the eyes and upper respiratory tract. L12265 casno 58052805 synonyms hexahydro2,4,6trimethylstriazine trihydrate recommended use laboratory chemicals. Acetaldehyde and hydrocyanic acid react to give lactonitrile ahydroxypropionitrile, a possible intermediate in acrylonitrile production 30. A violent reaction occurs between iodine and acetaldehyde, acetylene, acetaldehyde, strong oxidizing agents. Kawasaki department of applied chemistry, faculty of engineering, nagoya university, chikusaku, nagoya, japan received 17 december 1963 abstracthe reaction of acetaldehyde and ammonia to form ocaminoethanol in water and aqueous tbutanolic. Uses advised against food, drug, pesticide or biocidal product use. The ph dependency of the reaction of acetaldehyde and ammonia to form the acetaldehydeammonia trimer has been studied in detail. It is hygroscopic, and can be found in a trihydrate form. Chemical product and company identification product name. Skin contact wash off immediately with plenty of water for at least 15 minutes. Obtain special instructions before use wash skin thoroughly after handling use only outdoors or in a wellventilated area. K filters, whatever the class, are required to be marked with at least the filter type, the colour code green, together with the filter class, e.
Incompatibility of common laboratory chemicals when certain hazardous chemicals are stored or mixed together, violent reactions may occur because the chemicals are unsuitable for mixing, or are incompatible. Acetaldehyde ammonia trimer is a chemical compound described by the formula ch 3 chnh 3. Readily decomposes into acetaldehyde and ammonia when heated, causing the hazards of those substances lewis. The ph dependency of the reaction of acetaldehyde and ammonia to form the acetaldehyde ammonia trimer has been studied in detail. May be an explosion hazard, expecially in confined. Place the crude acetaldehyde in a florence flask of suitable volume to contain no more than two thirds of the liquid. Acetaldehyde is mildly irritating to the eyes and the upper respiratory tract. Acetaldehyde is an irritant of the skin, eyes, mucous membranes, throat, and respiratory tract. Buy acetaldehyde ammonia trimer cas 58052805, a biochemical for proteomics research, from santa cruz. It is therefore converted to aldehyde ammonia, then back to pure aldehyde. This control solution can be used when there is some doubt about the method accuracy. Hexahydro2,4,6trimethylstriazine trihydrate company identification. When heated to decomposition it emits toxic fumes of nh 3 and no x.
Acetaldehyde naturally breaks down in the human body but has been shown to excrete in urine of rats. Acetaldehyde is polymerized violently by concentrated sulfuric acid. Acetaldehyde can enter the brain and is the cause of the damage that occurs when drinking or smoking. It can also be used as an organic building block in the synthesis of 1,2dihydro1,3dimethyl 3 h naphth1.
Identification acetaldehyde ammonia is a colorless, white, yellow or brown. The acetaldehyde ammonia trimer is a molecule of interest in organic synthesis, since it can be used as a substrate in many reactions involving acetaldehyde or ammonia. It can also be used as an organic building block in the synthesis of 1,2dihydro1,3dimethyl3hnaphth1. Anhydrous ammonia safety data sheet tanner industries. Buy high purity acetaldehyde ammonia trimer, trihydrate analytical standards from chem service inc. Acetaldehyde control 2 g of acetaldehyde ammonia trimer. Personal protective clothing may become brittle when exposed to liquid ammonia. It is therefore converted to aldehydeammonia, then back to pure aldehyde. Reaction mechanism of aldehydes and ammonia to form.
Show this safety data sheet to the doctor in attendance. Based on these results, a reaction mechanism was proposed for the formation of 3methyl pyridine from acrolein and ammonia, and also, a general rule was summarized for the reaction of aldehyde. Acetaldehyde ammonia reacts with strong oxidizing agents and halogens. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and face protection regulations in 29 cfr 1910. Acetaldehyde is a member of a reactive family of molecules called aldehydes.
The crude acetaldehyde thus obtained is difficult to distill from the alcohol and acetal mixed with it. In individuals with normal metabolism, acetaldehyde is quickly converted into harmless acetic acid by a functioning aldh2 enzyme, and is then metabolized for energy. Anhydrous ammonia msds number 2001 revised april 23, 2008 10 pages 1. No warranty, express or implied, is made and labchem inc. Material safety data sheet msds ammonia page 2 of 3 afrox is a member of the linde group page 2 of 3 the stripe symbol and the word afrox are afrox group trademarks. Reaction mechanism of aldehydes and ammonia to form pyridine. Acetaldehyde is expected to be broken down by microorganisms and may not build up the tissues of in aquatic organisms. Threshold limit values tlv and immediately dangerous to life and health idlh values tlv tlv substance twa stel idlh tlv tlv substance twa stel idlh acetaldehyde 25c 2,000 acetic acid 10 15 50 acetone 500 750 2,500 acetonitirle 20 500 acrolein 0. Acetaldehyde is toxic clarification needed when applied externally for prolonged periods, an irritant, and a probable carcinogen. Dry ammonia forms crystalline acetaldehyde ammonia.
In case of skin contact wash off with soap and plenty of water. Seek medical advice if discomfort or irritation persists. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Where anhydrous ammonia is stored indoors, use electrical ventilating, lighting and material handling equipment with the appropriate electrical classification rating and use only nonsparking tools protective measures put on appropriate personal protective equipment see section 8.
Safety data sheet ammonia solution 24,9% section 1. Anhydrous ammonia reacts to form explosive products, mixtures or compounds with mercury, gold, silver, iodine, bromine, silver oxide and silver chloride. Cutaneous erythema has also been observed in the patch testing of humans. Ammonia forms sensitive explosive mixtures with air and hydrocarbons, ethanol and silver nitrate, and chlorine.
For use against ammonia and organic ammonia derivatives as specified by the manufacturer. Contact can irritate and may burn the eyes and skin. If inhaled if breathed in, move person into fresh air. Material safety data sheet ammonium thiocyanate, acs.
Page 1 of 7 propionaldehyde cas no 123386 material safety data sheet sdsmsds section 1. Acetaldehyde is the a metabolite of ethanol in humans and has been implicated as the active agent damaging the liver in ethanolinduced liver disease. Firstaid measures general advice if symptoms persist, call a physician. The information contained in this msds is applicable to the contents of. Passing ammonia gas over magnesium perchlorate dessicant causes intensive drying of ammonia gas which leads to an exothermic, followed by a violent explosion. Identification product name acetaldehyde ammonia trimer cat no. The user must determine suitability of this information for his application. However, we make no warranty of merchantability or any other. This fact sheet is a summary source of information of all potential and most severe health hazards that may result. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Safety data sheet northwest missouri state university.
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